EPR-SPECTRA OF NANOCRYSTALLINE COMPOSITE OXIDE LAFEO3 WITH THE PEROVSKITE STRUCTURE

被引:5
|
作者
LI, X [1 ]
ZHANG, HB [1 ]
ZHAO, MY [1 ]
ZHENG, YG [1 ]
机构
[1] JILIN UNIV,CTR MEASUREMENT & TEST,CHANGCHUN 130023,PEOPLES R CHINA
关键词
D O I
10.1016/0254-0584(94)90005-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocrystals of LaFeO3 with mean grain diameters of 12.4, 12.6, 14.4, 16.0 and 16.3 nm were compacted into pellets under static pressure of 0.5, 1.0 and 1.5 GPa in the axial direction at room temperature. Their EPR spectra change with grain sizes and compacted pressures. The results show that the g values increase a little with the increment of compacted pressures, whereas the peak intensities of EPR spectra of nanocrystalline materials are about 10(3) times as strong as those of conventional materials. This paper discusses characteristics of EPR spectra of nanocrystalline composite oxide LaFeO3.
引用
收藏
页码:157 / 161
页数:5
相关论文
共 50 条
  • [1] EPR-SPECTRA OF NANOCRYSTALLINE COMPOSITE OXIDES LA1-XSRXFEO3 WITH A PEROVSKITE STRUCTURE
    LI, X
    ZHANG, HB
    LI, SJ
    XIN, YQ
    ZHAO, MY
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 190 (02) : 287 - 290
  • [2] SYNTHETIC STUDIES OF NANOCRYSTALLINE COMPOSITE OXIDES WITH THE PEROVSKITE STRUCTURE BASED ON LAFEO3
    LI, X
    ZHANG, HB
    JIAO, QZ
    LI, SJ
    ZHAO, MY
    [J]. MATERIALS LETTERS, 1992, 15 (03) : 175 - 179
  • [3] XPS STUDY ON O(1S) ACID FE(2P) FOR NANOCRYSTALLINE COMPOSITE OXIDE LAFEO3 WITH THE PEROVSKITE STRUCTURE
    LI, X
    ZHANG, HB
    LIU, XX
    LI, SJ
    ZHAO, MY
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 1994, 38 (04) : 355 - 362
  • [4] Gas sensing with semiconducting perovskite oxide LaFeO3
    Toan, NN
    Saukko, S
    Lantto, V
    [J]. PHYSICA B-CONDENSED MATTER, 2003, 327 (2-4) : 279 - 282
  • [5] Combustion synthesis of nanocrystalline LaFeO3
    Ita, BI
    [J]. ACH-MODELS IN CHEMISTRY, 2000, 137 (5-6): : 671 - 676
  • [6] Sonochemical synthesis of nanocrystalline LaFeO3
    Sivakumar, A
    Gedanken, A
    Zhong, W
    Jiang, YH
    Du, YW
    Brukental, I
    Bhattacharya, D
    Yeshurun, Y
    Nowik, I
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (04) : 764 - 769
  • [7] Vibrational structure of EPR-spectra?
    Ortega, S.
    Handel, L. D.
    Passeggi, M. C.
    Buch, T.
    [J]. CHEMICAL PHYSICS LETTERS, 1969, 3 (01) : 35 - 36
  • [8] Thermal evolution of the crystal structure of the orthorhombic perovskite LaFeO3
    Dixon, Charlotte A. L.
    Kavanagh, Christopher M.
    Knight, Kevin S.
    Kockelmann, Winfried
    Morrison, Finlay D.
    Lightfoot, Philip
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2015, 230 : 337 - 342
  • [9] Synthesis of fibrous LaFeO3 perovskite oxide for adsorption of Rhodamine B
    Deng, Hui
    Mao, Zhiping
    Xu, Hong
    Zhang, Liping
    Zhong, Yi
    Sui, Xiaofeng
    [J]. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2019, 168 : 35 - 44
  • [10] EPR spectra of the nanocrystalline composite oxides La1-xSrxFe1-yCoyO3 with the perovskite structure
    Li, X
    Peng, ZY
    Fan, W
    Gu, JM
    Kui, G
    Zhao, MY
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 1996, 46 (01) : 31 - 35