ADIABATICITY RESTRICTIONS IN THE COLLISIONAL ENERGY-TRANSFER FROM HIGHLY EXCITED POLYATOMIC-MOLECULES

被引：23

作者：

DASHEVSKAYA, EI ^{[1
]}

NIKITIN, EE ^{[1
]}

OREF, I ^{[1
]}

机构：

[1] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,IL-32000 HAIFA,ISRAEL

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 37期

关键词：

D O I：

10.1021/j100139a024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A model is suggested which yields a correlation of the mean energy transferred in collisions of a highly excited polyatomic molecule with noble gas atoms. The model is based on consecutive direct encounters in a collision complex and incorporates the interplay between increasing interaction strength and decreasing energy-transfer efficiency due to the adiabaticity constraint. The model is illustrated by applying it to energy transfer in azulene-noble gas atom collisions.

引用

页码：9397 / 9402

页数：6

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