STUDY ON CHEMILUMINESCENCE FROM REACTIONS F-ATOM WITH CH3CN AND CH3CH2CN

被引：0

作者：

CHU, YN ^{[1
]}

ZHOU, SK ^{[1
]}

YANG, X ^{[1
]}

LIU, J ^{[1
]}

SONG, FQ ^{[1
]}

SHI, JL ^{[1
]}

机构：

[1] ACAD SINICA,INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

来源：

ACTA CHIMICA SINICA | 1993年 / 51卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemiluminescence in the visible region (400 approximately 900 nm) was measured from the reaction of F(2P) atoms with CH3CN and CH3CH2CN under low and high pressure conditions. Emissions were observed from vibrationally excited HF(double dagger)(X) and from electronically excited CN*(A) and CH*(A, B). The Franck-Condon factors of ON(A --> X) transitions was calculated, and the relative vibrational population of CN(A) was obtained. The formation mechanism of CN*(A2II) was suggested by the dissociation of the activated molecule like (CH2CNF)*.

引用

页码：910 / 914

页数：5

共 14 条

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