ELECTRON-TRANSFER RATES IN A TRINUCLEAR MIXED-VALENCE IRON(III,III,II) MOLECULE - A VARIABLE-TEMPERATURE INFRARED SPECTROSCOPIC STUDY

被引：30
|
作者：
WU, RW [1 ]
KOSKE, SKA [1 ]
WHITE, RP [1 ]
ANSON, CE [1 ]
JAYASOORIYA, UA [1 ]
CANNON, RD [1 ]
机构：
[1] UNIV E ANGLIA, SCH CHEM SCI, NORWICH NR4 7TJ, NORFOLK, ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期
关键词：
D O I：
10.1039/c39940001657
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In IR spectra of the mixed-valence compound [(Fe2FeII)-Fe-III(OOCCMe(3))(6)(C5D5N)(3)], the bands assigned to in-plane vibration of the central oxygen atom show exceptional temperature dependence, interpreted as being due to electron transfer within the trinuclear cluster, with a rate constant of ca. 10(11) s(-1) at 300 K.
引用
收藏
页码：1657 / 1658
页数：2
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