BULK AND SURFACE-DIFFUSION IN POROUS-MEDIA - AN APPLICATION OF THE SURFACE-AVERAGING THEOREM

被引:0
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作者
OCHOATAPIA, JA
DELRIO, JA
WHITAKER, S
机构
[1] UNIV CALIF DAVIS, DEPT CHEM ENGN, DAVIS, CA 95616 USA
[2] INST TECNOL CELAYA, DEPT INGN QUIM, CELAYA 38010, GUANAJUATO, MEXICO
[3] Univ Nacl Autonoma Mexico, IIM, ENERGIA SOLAR LAB, ZONA CULTURAL XOCHICALO, TEMIXCO 62580, MORELOS, MEXICO
关键词
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A general treatment of bulk and surface diffusion is presented in terms of the method of volume averaging. In addition to the spatial-averaging theorem, the analysis requires the surface-averaging theorem, which is derived using only routine three-space vector analysis. The closure problem is formulated and overall effective diffusivities are calculated using Chang's unit cell, which leads to Maxwell's model.
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页码:2061 / 2082
页数:22
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