SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF RE4(NBUT)8(MU-O)2(MU-3-O)2(OSO2CF3)4

被引：8

作者：

LAM, HW

WILKINSON, G ^{[1
]}

WILLIAMS, DJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,JOHNSON MATTHEY LAB,LONDON SW7 2AY,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)81340-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of Re(NBu(t))3(NHBu(t)) and CF3SO3H in Et2O leads to the known [Re(NBu(t))3(NH2Bu(t))]O3SCF3 but also to a low yield, presumably via a competitive reaction, of a red compound, Re4(NBu(t))8(mu-O)2(mu-3-O)2(OSO2CF3)4, whose X-ray crystal structure has been determined. The structure has a Re4O4 core comprising oxo-bridged, five- and six-coordinate rhenium centres. The six-coordinate rhenium centres have cis oriented oxo, NBu(t) and eta-1-O3SCF3 ligands; the five-coordinate centres have pairs of NBu(t) and mu-3-O ligands and a mu-O ligand.

引用

页码：2647 / 2650

页数：4

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