THE KINETICS OF CYCLOHEXANE OXIDATION BY MOLECULAR-OXYGEN IN THE PRESENCE OF IRON PORPHYRINS AND A REDUCING AGENT

被引：0
|
作者：
KARASEVICH, EI
ANISIMOVA, BL
RUBAILO, VL
SHILOV, AE
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来源：
KINETICS AND CATALYSIS | 1993年 / 34卷 / 04期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of C6H12 oxidation is studied using GLC by the accumulation of products. The oxidation is accompanied by the reductive activation of molecular oxygen by iron porphyrins containing various substituents in phenyl rings. The experiments were performed at room temperature in the CH3CN-carboxylic acid-Zn system with and without methyl viologen. A scheme of oxygen activation during the oxidation of hydrocarbons is proposed.
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页码：577 / 582
页数：6
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