FIRST ENANTIOSELECTIVE SYNTHESIS OF MIKANECIC ACID VIA DIELS-ALDER CYCLOADDITION MEDIATED CONSTRUCTION OF CHIRAL VINYLIC QUATERNARY CENTER

被引：32
|
作者：
BASAVAIAH, D
PANDIARAJU, S
SARMA, PKS
机构：
[1] School of Chemistry, University of Hyderabad, Hyderabad
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 24期
关键词：
D O I：
10.1016/S0040-4039(00)73158-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral mikanecic acid (1) was synthesized in 74% enantiomeric purity (92% ee after crystallization) via asymmetric Diels-Alder reaction of a novel in situ generated chiral 1,3-butadiene-2-carboxylate (A).
引用
收藏
页码：4227 / 4230
页数：4
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