COLOR-REACTION OF PLATINUM(II) WITH 5-(4-NITROPHENYLAZO)-8-(PARA-TOLUENESULPHONAMIDO)QUINOLINE AND ITS ANALYTICAL APPLICATIONS

被引：7

作者：

ZHAO, JW ^{[1
]}

XU, QH ^{[1
]}

机构：

[1] YUNNAN UNIV,DEPT CHEM,KUNMING 650091,PEOPLES R CHINA

来源：

TALANTA | 1991年 / 38卷 / 08期

关键词：

SPECTROPHOTOMETRIC DETERMINATION; SEPARATION;

D O I：

10.1016/0039-9140(91)80271-Z

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A simple, rapid and sensitive spectrophotometric method has been developed for the determination of platinum. 5-(4-Nitrophenylazo)-8-(p-toluenesulphonamido)quinoline (NPTSQ) reacts with platinum(II) almost instantaneously in alkaline solution to form a violet-red 1:2 complex with an absorption maximum at 640 nm. Beer's law is obeyed over the concentration range 0-1-mu-g/ml platinum. The molar absorptivity is 1.37 x 10(5) l.mole-1.cm-1. The method has been used for the determination of microamounts of platinum in catalysts and anode slime.

引用

页码：909 / 912

页数：4

共 13 条

[1] COLOR-REACTION OF GOLD WITH 5-(4-SODIUM SULPHONATEPHENYLAZO)-8-AMINOQUINOLINE AND ITS ANALYTICAL APPLICATION
ZENG, ZT
XU, QH
TALANTA, 1992, 39 (04) : 409 - 413
[2] FLUORESCENCE REACTION OF 5-(P-METHOXYPHENYLAZO)-8-(P-TOLYLSULFONAMIDO)QUINOLINE WITH COBALT(II) AND ITS ANALYTICAL APPLICATION
ZENG, ZT
XU, QH
ANALYTICAL LETTERS, 1992, 25 (08) : 1573 - 1579
[3] Solvent effect on the self-adduct extraction of zinc(II) with 5-(4-nitrophenylazo)-7-(4--ethyl-1-methyloctyl)-8-quinolinol
Ohashi, K
Matsuta, N
Imura, H
Yamamoto, H
Hiratani, K
BUNSEKI KAGAKU, 1998, 47 (02) : 101 - 107
[4] Synthesis of 5-(4-sulfanoylphenylazo)-8-aminoquinoline and its color reaction with cobalt (II)
Xu, Jiming
Wu, Bincai
Lihua Jianyan: Huaxue Fence/Physical Testing and Chemical Analysis Part B:Chemical Analysis, 2000, 36 (12): : 543 - 544
[5] Synthesis of 8-(8-quinolylazo)-5-aminoquinoline and its color reaction with cobalt(II)
Department of Chemistry, Zunyi Normal College, Zunyi 563002, China
不详
Yejin Fenxi, 2007, 2 (33-36):
[6] Study on the color reaction of palladium with 8-[calix(4) arene] aminoquinoline and its analytical application
Huang, Zhang-Jie
Hu, Qiu-Fen
Yin, Jia-Yuan
Chen, Jia-Xi
Yejin Fenxi/Metallurgical Analysis, 2002, 22 (03):
[7] Synergistic effect of tri-n-octylphosphine oxide upon extractive separation of zinc(II) and cadmium(II) by 5-(4-nitrophenylazo)-7-(4-ethyl-1-methyloctyl)-8-quinolinol
Ohashi, K
Matsuta, N
Imura, H
BUNSEKI KAGAKU, 2001, 50 (07) : 493 - 499
[8] STUDY OF THE COLOR-REACTION OF COBALT (II) WITH 5-(5-CHLORO-2-PIRIDILAZO) 2,4-DIAMINOTOLUENE (5-CL-PADAT) - APPLICATIONS
QIU, XC
ZHU, YQ
ZHANG, L
REVISTA DE CHIMIE, 1986, 37 (07): : 586 - 588
[9] Colour reaction of chromogenic reagent 1-(5-carboxy-1,3,4-triazolyl)-3-[4-(4-nitrophenylazo)phenyl]-triazene with cadmium (II) and its application
Meng, SM
Fang, GZ
Guo, Y
Pan, JM
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2002, 30 (01) : 123 - 123
[10] Synthesis of 5-[2-(5-ethyl-1, 3, 4-thiodiazole)azo]-8-hydroxyquinoline and its color reaction with copper (II)
Applied Chemistry Department, East China Institute of Technology, Fuzhou 344000, China
Yejin Fenxi, 2007, 10 (32-35): : 32 - 35

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