STUDIES ON FUSED PYRIMIDINE-DERIVATIVES .9. THERMAL-REACTIONS OF 6-METHYL-5-[(SUBSTITUTED HYDRAZONO)METHYL]-2,4(1H,3H)-PYRIMIDINEDIONES WITH ELECTRON-DEFICIENT OLEFINS AND ACETYLENE

被引：12
|
作者：
NOGUCHI, M
KIRIKI, Y
TSURUOKA, T
MIZUI, T
KAJIGAESHI, S
机构：
[1] Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University, Tokiwadai, Ube
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 01期
关键词：
D O I：
10.1246/bcsj.64.99
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermal reactions of some 6-methyl-5-[(substituted hydrazino)methyl]-2,4(1H,3H)-pyrimidinediones (1) were investigated. The 1,5-hydrogen shift in 1 gave 5,6-dihydro-5,6-bis(methylene)-2,4(1H,3H)-pyrimidinedione intermediates, while the 1,2-hydrogen shift in 1 gave azomethine imine intermediates. These reaction profiles depend on the substituents of hydrazone moieties.
引用
收藏
页码：99 / 105
页数：7
相关论文
共 50 条
  • [1] PYRIMIDINE-DERIVATIVES .9. SYNTHESIS OF BROMO-SUBSTITUTED 5-NITRO-2,4(1H,3H)-PYRIMIDINEDIONE DERIVATIVES
    KINOSHITA, T
    WATANABE, Y
    NAKAO, S
    FURUKAWA, S
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1992, 29 (07) : 1785 - 1788
  • [2] PYRIMIDINE-DERIVATIVES .7. NUCLEOPHILIC REACTIONS OF 5-BROMO-1-(BROMOALKYL)-6-BROMOMETHYL-2,4(1H,3H)-PYRIMIDINEDIONES
    KINOSHITA, T
    TAKAISHI, Y
    OKUNAKA, T
    OHWADA, T
    FURUKAWA, S
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1992, 29 (04) : 741 - 747
  • [3] PYRIMIDINE-DERIVATIVES .5. SYNTHESIS AND NUCLEOPHILIC REACTIONS OF 5-BROMO-6-BROMOMETHYL-1-(2-BROMOETHYL AND 2-BROMOPROPYL)-3-METHYL-2,4(1H,3H)-PYRIMIDINEDIONE
    KINOSHITA, T
    NAKAHATA, N
    KOUCHI, A
    FURUKAWA, S
    [J]. CHEMICAL & PHARMACEUTICAL BULLETIN, 1988, 36 (10) : 3887 - 3896
  • [4] STUDIES ON FUSED PYRIMIDINE-DERIVATIVES .13. THERMAL ENE REACTION OF 6-(ALK-2-ENYLAMINO)-5-[(SUBSTITUTED IMINO)METHYL]-1,3-DIMETHYLPYRIMIDINE-2,4(1H,3H)-DIONES LEADING TO PYRIMIDO[4,5-B]AZEPINES
    INAZUMI, T
    HARADA, E
    MIZUKOSHI, T
    KUROKI, Y
    KAKEHI, A
    NOGUCHI, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (05): : 565 - 570
  • [5] PERMANGANATE ION OXIDATIONS .9. MANGANESE INTERMEDIATES (COMPLEXES) IN OXIDATION OF 2,4(1H,3H)-PYRIMIDINEDIONES
    FREEMAN, F
    KARCHEFSKI, EM
    [J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1976, 447 (02) : 238 - 245
  • [6] 1,3-Bis(4-methoxybenzyl)-6-methyl-pyrimidine-2,4(1H,3H)-dione
    Li, Gong-Chun
    Zhang, Li-Ke
    Ju, Zhi-Yu
    Yang, Feng-Ling
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1858 - U1031
  • [7] Aminomethylation of 6-methyl-1-(thietan-3-yl)pyrimidine-2,4(1H,3H)-dione
    Meshcheryakova, S. A.
    Kataev, V. A.
    Munasipova, D. A.
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 50 (03) : 422 - 424
  • [8] Aminomethylation of 6-methyl-1-(thietan-3-yl)pyrimidine-2,4(1H,3H)-dione
    S. A. Meshcheryakova
    V. A. Kataev
    D. A. Munasipova
    [J]. Russian Journal of Organic Chemistry, 2014, 50 : 422 - 424
  • [9] 6-(3,5-Dimethylbenzyl)-5-ethyl-1-[(2-phenylethoxy)methyl]pyrimidine-2,4(1H,3H)dione
    El-Brollosy, Nasser R.
    Attia, Mohamed I.
    Ghabbour, Hazem A.
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1031 - +
  • [10] STUDIES ON FUSED PYRIMIDINE-DERIVATIVES .12. REACTION OF 6-(ALK-2-ENYLAMINO)-5-FORMYL-1,3-DIMETHYLPYRIMIDINE-2,4(1H,3H)-DIONES WITH ALPHA-AMINO-ACID DERIVATIVES
    INAZUMI, T
    YAMADA, K
    KUROKI, Y
    KAKEHI, A
    NOGUCHI, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (05): : 557 - 564
12345