CATIONIC PALLADIUM(II), PLATINUM(II), AND RHODIUM(I) COMPLEXES AS ACETALIZATION CATALYSTS

被引：55
|
作者：
GORLA, F [1 ]
VENANZI, LM [1 ]
机构：
[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,UNIV STR 6,CH-8092 ZURICH,SWITZERLAND
来源：
HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 03期
关键词：
D O I：
10.1002/hlca.19900730317
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The use of [Pd(H2O)2(Ph2PCH2CH2PPh2)] (CF3SO3)2 as a catalyst for the acetalisation of a variety of aldehydes and ketones and for trans‐acetalisation is described. It is also shown that Pt(H2O)2(PH2PCH2CH2PPh2) (CF3SO3)2 is at least as effective as the corresponding Pd compound, while much lower reaction rates are observed with [Rh(MeOH)2(Ph2PCH2CH2PPh2)] [BF4]. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim
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页码：690 / 697
页数：8
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