CONCURRENT ACYLATION AND ALKYLATION IN THE FRIEDEL-CRAFTS REACTION OF FERROCENE WITH TRIMETHYLACETYL CHLORIDE

被引：0
|
作者：
BELL, W [1 ]
GLIDEWELL, C [1 ]
机构：
[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1991年 / 02期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Whereas the reaction of ferrocene with a stoichiometric quantity of Me3CCOCl-AlCl3 provides the monoacylated product in 87% yield, the use of an excess of the acylation reagent leads to simultaneous acylation and alkylation, two products of which have been isolated and characterised by NMR spectroscopy.
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页码：44 / 45
页数：2
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