DIGITAL-SIMULATION OF CHARGE-TRANSFER TO AN ULTRAMICRODISC INTERFACE

被引：46
|
作者：
TAYLOR, G
GIRAULT, HH
MCALEER, J
机构：
[1] DEPT CHEM,KINGS BLDGS,W MAINS RD,EDINBURGH EH9 3JJ,SCOTLAND
[2] MEDISENSE UK INC,ABINGDON OX14 1DY,OXON,ENGLAND
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 293卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(90)80050-G
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A novel space-grid expansion in two dimensions coupled with an ADI method allowing implicit determination of boundary concentrations is presented. These yield a fast and accurate algorithm applied to cyclic voltammetry and chronoamperometry for reversible, quasi-reversible and irreversible charge transfer at ultramicrodisc interfaces. The effects of the kinetic parameters k, Λ, α on current-potential-time response curves are studied. © 1990.
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页码：19 / 44
页数：26
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