STABILIZATION OF COPPER(I) BY PHOSPHINOAMINES

被引：13

作者：

TISATO, F

REFOSCO, F

BANDOLI, G

PILLONI, G

CORAIN, B

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-35131 PADUA,ITALY

[2] CNR,CTR STUDIO STABIL & REATTIV COMPOSTI COORDINAZ,I-35131 PADUA,ITALY

[3] UNIV PADUA,DIPARTIMENTO SCI FARMACEUT,I-35131 PADUA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 16期

关键词：

D O I：

10.1039/dt9940002471

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetradentate phosphinoamines N,N'-bis[2-(diphenylphosphino)phenyl]ethane-1,2-diamine (H-2dpen) and N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine stabilize copper(I) complexes either by ligand-exchange reactions from labile [Cu(I)(MeCN)4]+ or ligand-promoted reduction of a Cu(III)Cl2.2H2O precursor; the structure of one of the products, [Cu(H-2dpen)]BF4, has been determined.

引用

页码：2471 / 2472

页数：2

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