SYNTHESIS AND CHARACTERIZATION OF [N(PPH3)2]+ CYANOMETALATES - CRYSTAL-STRUCTURE OF [N(PPH3)2]3[FE(CN)6].2H2O

被引：9

作者：

CAUZZI, DA

MORI, G

PREDIERI, G

TIRIPICCHIO, A

CAVATORTA, F

机构：

[1] UNIV PARMA,IST CHIM GEN & INORGAN,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,VIALE SCI,I-43100 PARMA,ITALY

[2] UNIV PARMA,DIPARTIMENTO FIS,I-43100 PARMA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 204卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)82923-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex salts [N(PPh3)2]n[M(CN)6] (M = Fe, n = 3 or 4; M = Ru, n = 4; M = Co, n = 3) and [N(PPh3)2]2-[Fe(CN)5(NO)] have been prepared by metathetical reactions between [N(PPh3)2]Cl and the corresponding alkaline cyanometallates. The iron(II) and ruthenium(II) hexacyano complexes are rather unstable in the air, the former being completely oxidized in a short time even in the solid state. All compounds have been characterized by spectroscopic techniques. The crystal structure of [N(PPh3)2]3[Fe(CN)6].2H2O has been determined by X-ray diffraction methods.

引用

页码：181 / 187

页数：7

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