SUBSTITUENT EFFECTS ON THE PHOTOSOLVOLYSES OF 2-CHLOROPROPIOPHENONES IN 2,2,2-TRIFLUOROETHANOL

被引：2
|
作者：
USUI, S
NISHIMOTO, J
OHKUBO, K
机构：
[1] KUMAMOTO UNIV, FAC ENGN, DEPT APPL CHEM, KUMAMOTO 860, JAPAN
[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN
来源：
CHEMISTRY LETTERS | 1994年 / 11期
关键词：
D O I：
10.1246/cl.1994.2015
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The substituent effects on the product distributions of the photosolvolyses of 2-chloropropiophenones in 2,2,2-trifluoroethanol were investigated. A pi-electron-donating methoxy substituent at p- and m-position enhanced the heterolytic product of the nucleophilic substitution over that of phenyl-rearrangement.
引用
收藏
页码：2015 / 2016
页数：2
相关论文
共 50 条
  • [1] 2,2,2-Trifluoroethanol
    Schwertfeger, Hartmut
    [J]. SYNLETT, 2010, (19) : 2971 - 2972
  • [2] NUCLEOPHILICITY OF 2,2,2-TRIFLUOROETHANOL
    BENTLEY, MD
    LACADIE, JA
    [J]. TETRAHEDRON LETTERS, 1971, (10) : 741 - &
  • [3] THE PREPARATION OF 2,2,2-TRIFLUOROETHANOL
    GILMAN, H
    JONES, RG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (03) : 1281 - 1282
  • [4] Atmospheric Reactions of 2,2,2-Trifluoroethanol
    E. S. Vasil'ev
    I. I. Morozov
    W. Hack
    K. Hoyermann
    M. Hold
    Yu. I. Dorofeev
    [J]. Doklady Physical Chemistry, 2001, 381 : 293 - 297
  • [5] A comparison of the properties of 2,2,2-trifluoroethanol and 2,2,2-trifluoroethanol/water mixtures using different force fields
    Chitra, R
    Smith, PE
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (12): : 5521 - 5530
  • [6] Interactions of 2,2,2-trifluoroethanol with melittin
    Neuman, Robert C., Jr.
    Gerig, John T.
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 2009, 47 (11) : 925 - 931
  • [7] ANIMAL TOXICITY OF 2,2,2-TRIFLUOROETHANOL
    BLAKE, DA
    CASCORBI, HF
    ROZMAN, RS
    MEYER, FJ
    [J]. TOXICOLOGY AND APPLIED PHARMACOLOGY, 1969, 15 (01) : 83 - &
  • [8] Atmospheric reactions of 2,2,2-trifluoroethanol
    Vasil'ev, ES
    Morozov, II
    Hack, W
    Hoyermann, K
    Hold, M
    Dorofeev, YI
    [J]. DOKLADY PHYSICAL CHEMISTRY, 2001, 381 (4-6) : 293 - 297
  • [9] Hydrogen bonding in 2,2,2-trifluoroethanol
    Ng, Soon
    Xie, Yaoming
    Schaefer III, Henry F.
    [J]. JOURNAL OF MOLECULAR MODELING, 2024, 30 (10)
  • [10] THERMODYNAMIC PROPERTIES OF 2,2,2-TRIFLUOROETHANOL
    MALHOTRA, R
    WOOLF, LA
    [J]. INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1991, 12 (02) : 397 - 407
12345