ACID-BASE BIFUNCTIONAL CATALYSIS BY ZRO2 AND ITS MIXED OXIDES

被引：279
|
作者：
TANABE, K [1 ]
YAMAGUCHI, T [1 ]
机构：
[1] HOKKAIDO UNIV,FAC SCI,DEPT CHEM,SAPPORO,HOKKAIDO 060,JAPAN
来源：
CATALYSIS TODAY | 1994年 / 20卷 / 02期
关键词：
D O I：
10.1016/0920-5861(94)80002-2
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Examples of acid-base bifunctional catalysis by ZrO2 and its mixed oxides are summarized. The hydrogenation of olefins, carbon monoxide and aromatic carboxylic acids over ZrO2 are also examples of acid-base bifunctional catalysis which occur by heterolytic splitting of a hydrogen molecule (H-2) into a proton (H+) and a hydride ion (H-) on the acid-base pair sites. Industrial applications of ZrO2 catalysts are demonstrated, the importance of acid-base bifunctional catalysis by ZrO2 and its mixed oxides being emphasized.
引用
收藏
页码：185 / 198
页数：14
相关论文
共 50 条
  • [1] ACID-BASE BIFUNCTIONAL CATALYSIS
    TANABE, K
    [J]. ACID-BASE CATALYSIS, 1989, : 513 - 527
  • [2] BIFUNCTIONAL ACID-BASE CATALYSIS OF THE MUTAROTATION OF GLUCOSE IN MIXED AQUEOUS SOLVENTS
    KJAER, AM
    NIELSEN, H
    SORENSEN, PE
    ULSTRUP, J
    [J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1980, 34 (04): : 281 - 288
  • [3] ACID-BASE BIFUNCTIONAL CATALYSIS IN THE DECOMPOSITION OF ALKYLAMINES
    XU, BQ
    YAMAGUCHI, T
    TANABE, K
    [J]. APPLIED CATALYSIS, 1991, 75 (01): : 75 - 86
  • [4] Cooperative catalysis by acid-base bifunctional graphene
    Li, Yang
    Zhao, Qingshan
    Ji, Junyi
    Zhang, Guoliang
    Zhang, Fengbao
    Fan, Xiaobin
    [J]. RSC ADVANCES, 2013, 3 (33): : 13655 - 13658
  • [5] Acid-base bifunctional catalysis: An industrial viewpoint
    Setoyama, Tohru
    [J]. CATALYSIS TODAY, 2006, 116 (02) : 250 - 262
  • [6] ACID-BASE BIFUNCTIONAL BEHAVIOR OF ZRO2 IN DUAL ADSORPTION OF CO2 AND NH3
    XU, BQ
    YAMAGUCHI, T
    TANABE, K
    [J]. CHEMISTRY LETTERS, 1988, (10) : 1663 - 1666
  • [7] Constants of acid-base equilibria at the ZrO2/electrolyte interface
    Batrakov, VV
    Khlupov, AY
    Gorichev, IG
    Kostrikin, AV
    Izotov, AD
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2000, 74 : S553 - S558
  • [8] LEWIS ACIDITY AND SOME ACID-BASE INTERACTIONS AT THE SURFACE OF ZRO2
    MORTERRA, C
    MARCHESE, L
    [J]. ACID-BASE CATALYSIS, 1989, : 197 - 205
  • [9] Acid-Base properties of MgCuAl mixed oxides
    S. Casenave
    H. Martinez
    C. Guimon
    A. Auroux
    V. Hulea
    E. Dumitriu
    [J]. Journal of Thermal Analysis and Calorimetry, 2003, 72 : 191 - 198
  • [10] Acid-base properties of MgCuAl mixed oxides
    Casenave, S
    Martinez, H
    Guimon, C
    Auroux, A
    Hulea, V
    Dumitriu, E
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 72 (01) : 191 - 198
12345