GOLD CARBONYLS AND NITROSYLS IN HIGHLY DISPERSED AU(I) ON ZEOLITE NAY AND ZSM-5

被引：0
|
作者：
QIU, SL [1 ]
PANG, WQ [1 ]
XU, WG [1 ]
XU, RR [1 ]
机构：
[1] HOKKAIDO UNIV,DEPT CHEM,SAPPORO,HOKKAIDO,JAPAN
来源：
ZEOLITES AND RELATED MICROPOROUS MATERIALS: STATE OF THE ART 1994 | 1994年 / 84卷
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It was found by XRD study, coupled with XPS that the intrazeolite Au(I) carbonyls and nitrosyls are formed by the reductive carbonylation of highly dispersed Au(III)/NaY and Au(III)/ZSM-5 catalysts, which are prepared by either so-called monolayer dispersion method or microwave processing from a mixtures of AuCl3 and NaY or ZSM-5. They are catalytically active in NO reduction with CO towards N2O and CO2 at 293 - 373K.
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页码：1059 / 1066
页数：8
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