SYNTHESIS, STRUCTURE, AND METALATION OF 1,3,5-TRIS(DIMETHYLAMINO)BENZENE

被引：4
|
作者：
KUHN, N [1 ]
LAARZ, W [1 ]
SCHULTEN, M [1 ]
BOESE, R [1 ]
BLASER, D [1 ]
BRETT, WA [1 ]
STELLBERG, P [1 ]
机构：
[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 09期
关键词：
1,3,5-TRIS(DIMETHYLAMINO)BENZENE; SYNTHESIS; STRUCTURE; METALATION;
D O I：
10.1515/znb-1992-0904
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of 1,3,5-tris(dimethylamino)benzene (5, Ar-H) is reported. The X-ray structure of 5 reveals two independent molecules in the unit cell both containing planar arene rings; the puckering of the amino substituents is demonstrated to be a consequence of steric interactions. 5 is metalated by n-butyl-lithium to give the isolable aryl-lithium compound Ar- Li (6) from which the phosphane Ar-PCl2 (7) and silane Ar-SiCl3 (8) are obtained.
引用
收藏
页码：1233 / 1240
页数：8
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