SILYLATIVE DIMERIZATION OF AROMATIC-ALDEHYDES CATALYZED BY A THIOLATE-BRIDGED DIRUTHENIUM COMPLEX

被引：26
|
作者：
SHIMADA, H [1 ]
QU, JP [1 ]
MATSUZAKA, H [1 ]
ISHII, Y [1 ]
HIDAI, M [1 ]
机构：
[1] UNIV TOKYO,GRAD SCH ENGN,DEPT CHEM & BIOTECHNOL,BUNKYO KU,TOKYO 113,JAPAN
来源：
CHEMISTRY LETTERS | 1995年 / 08期
关键词：
D O I：
10.1246/cl.1995.671
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A cationic thiolate-bridged diruthenium complex [Cp(*)RuCl-(mu(2)-SPri)(2)RuCp(*)][OTf] (Cp* = eta(5)-C(5)Me(5), OTf = OSO2CF3) was found to be an efficient catalyst for the reaction of aromatic aldehydes with hydrosilanes in acetonitrile to give 1,2-diaryl-1,2-disiloxyethanes as the major products.
引用
收藏
页码：671 / 672
页数：2
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