PHTHALIMIDOSULFENYL CHLORIDE .5. REACTION WITH ENOLIZABLE CARBONYL-COMPOUNDS AND SYNTHESIS OF FUNCTIONALIZED THIONES

被引：52

作者：

CAPOZZI, G ^{[1
]}

MENICHETTI, S ^{[1
]}

NATIVI, C ^{[1
]}

ROSI, A ^{[1
]}

VALLE, G ^{[1
]}

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM ORGAN,CNR,CTR BIOPOLIMERI,I-35100 PADUA,ITALY

来源：

TETRAHEDRON | 1992年 / 48卷 / 41期

关键词：

PHTHALIMIDOSULPHENYL CHLORIDE REACTIONS WITH CARBONYL COMPOUNDS; SYNTHESIS AND CYCLOADDITIONS OF THIONES; SYNTHESIS OF 1-PHENYL-1-HYDROXYETHANTHIOLE;

D O I：

10.1016/S0040-4020(01)82000-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Beta-ketothio derivatives 4, prepared by reaction of phthalimidosulphenyl chloride with enolizable carbonyl compounds, afford, in presence of pyridine, unstable functionalized thiones which can be trapped with 1,3-dienes to give the corresponding cycloaddition products 8 and 9.

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页码：9023 / 9032

页数：10

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