CATALYTIC BEHAVIOR OF SELECTED TRANSITION-METAL CARBIDES, NITRIDES, AND BORIDES IN THE HYDRODENITROGENATION OF QUINOLINE

被引：251
|
作者：
SCHLATTER, JC
OYAMA, ST
METCALFE, JE
LAMBERT, JM
机构：
[1] CATALYTICA, MT VIEW, CA 94043 USA
[2] STAND OIL CO OHIO, INDEPENDENCE, OH 44131 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1988年 / 27卷 / 09期
关键词：
Aromatic Compounds--Chemical Reactions - Catalysts - Chemical Equipment--Reactors;
D O I：
10.1021/ie00081a014
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
High surface area carbides and nitrides have been synthesized and tested for hydrodenitrogenation activity. Some of the novel materials, particularly Mo2C and Mo2N, provided hydrodenitrogenation activity of the same magnitude as commercial sulfided Ni-Mo/Al2O3. In the absence of sulfur in the feed, the refractory catalysts could achieve denitrogenation with less hydrogen consumption than the commercial sample. Sulfur addition was detrimental to the selectivity, but not the activity of Mo2C and Mo2N.
引用
收藏
页码：1648 / 1653
页数：6
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