STUDIES ON BLENDS OF A THERMOTROPIC LIQUID-CRYSTALLINE POLYMER AND POLYBUTYLENE TEREPHTHALATE

被引:16
|
作者
HEINO, MT [1 ]
SEPPALA, JV [1 ]
机构
[1] HELSINKI UNIV TECHNOL,DEPT CHEM ENGN,KEMISTINTIE 1,SF-02150 ESPOO,FINLAND
关键词
D O I
10.1007/BF00343072
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Structure-property relationships of blends of a thermotropic polyester-type main-chain LCP and polybutylene terephthalate (PBT) were investigated. LCP was melt blended with three different PBTs and the blends were processed by injection moulding or extrusion. Mechanical and thermal properties of the blends were determined and the blend structure was characterized by scanning electron microscopy (SEM). LCP acted as mechanical reinforcement for PBT and improved also its dimensional and thermal stability. The stiffness of PBT increased with increasing LCP content, but at the same time the blends became more brittle. In extrusion the orientation of LCP phases could be further enhanced by additional drawing, which led to significant improvements in strength and stiffness at LCP contents of 20-30 wt.-%.
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页码:353 / 360
页数:8
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