PREPARATION AND MAGNETIC-PROPERTIES OF CU6O8.INCL AND LIXCU6O8.INCL

被引：2
|
作者：
PARANTHAMAN, M
STEINFINK, H
机构：
[1] Center for Materials Science and Engineering, The University of Texas at Austin, Austin
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1992年 / 96卷 / 01期
关键词：
D O I：
10.1016/S0022-4596(05)80317-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds Cu6O8·InCl and Li1.23Cu6O8·InCl were prepared. The powder X-ray diffraction pattern shows that both phases have the same cubic structure with a=9.144(5) Å. The introduction of Li+ lowers the average valence of copper. Neither phase superconducts above 5 K. Measurements of magnetic susceptibility show ferrimagnetic behavior for both phases, with an onset temperature of 125 K for the copper phase and 75 K for the lithiated phase. The copper phase shows a constant magnetization over the range 125-50 K that may be due to a two-sublattice antiferromagnetic interaction. © 1992 Academic Press, Inc.
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页码：243 / 246
页数：4
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