THE EFFECT OF HYDROGEN-SULFIDE ON ACRIDINE HYDRODENITROGENATION ON A SULFIDED NIMO/AL2O3 CATALYST

被引：11
|
作者：
NAGAI, M
机构：
[1] Department of Chemical Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 01期
关键词：
D O I：
10.1246/bcsj.64.330
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of hydrogen sulfide on acridine hydrodenitrogenation over a sulfided NiMo/Al2O3 catalyst at 280-380-degrees-C and 10.1 MPa total pressure was studied. The result showed that the presence of H2S depressed the total C-N hydrogenolysis at a low P(H2)S/P(H2) ratio of 1.1-79x10(-5), but that it rarely affected the C-N hydrogenolysis at a ratio above 0.003.
引用
收藏
页码：330 / 332
页数：3
相关论文
共 50 条
  • [1] The effect of hydrogen sulfide on acridine hydrodenitrogenation on a sulfided NiMo/Al2O3 catalyst
    Nagai, Masatoshi, 1600, Chemical Society of Japan (64):
  • [2] EFFECT OF HYDROGEN-SULFIDE ON THE CATALYTIC HYDRODENITROGENATION OF 1,2,3,4-TETRAHYDROQUINOLINE - COMPARISON OF NIMO/AL2O3 AND COMO/AL2O3
    BRUNET, S
    PEROT, G
    REACTION KINETICS AND CATALYSIS LETTERS, 1985, 29 (01): : 15 - 20
  • [3] Mechanism of the hydrodenitrogenation of neopentylamine and adamantylamine on sulfided NiMo/Al2O3
    Zhao, Y.
    Sivasankar, N.
    Czyzniewska, J.
    Kukula, P.
    Prins, R.
    CATALYSIS LETTERS, 2006, 110 (3-4) : 221 - 228
  • [4] Mechanism of the direct hydrodenitrogenation of naphthylamine on sulfided NiMo/Al2O3
    Zhao, Y
    Czyzniewska, J
    Prins, R
    CATALYSIS LETTERS, 2003, 88 (3-4) : 155 - 162
  • [5] Mechanism of the hydrodenitrogenation of neopentylamine and adamantylamine on sulfided NiMo/Al2O3
    Y. Zhao
    N. Sivasankar
    J. Czyzniewska
    P. Kukula
    R. Prins
    Catalysis Letters, 2006, 110 : 221 - 228
  • [6] Mechanism of the Direct Hydrodenitrogenation of Naphthylamine on Sulfided NiMo/Al2O3
    Y. Zhao
    J. Czyzniewska
    R. Prins
    Catalysis Letters, 2003, 88 : 155 - 162
  • [7] Role of hydrogenolysis and nucleophilic substitution in hydrodenitrogenation over sulfided NiMo/γ-Al2O3
    Rota, F
    Prins, R
    JOURNAL OF CATALYSIS, 2001, 202 (01) : 195 - 199
  • [8] Iminium cations as intermediates in the hydrodenitrogenation of alkylamines over sulfided NiMo/γ-Al2O3
    Sivasankar, N.
    Prins, R.
    CATALYSIS TODAY, 2006, 116 (04) : 542 - 553
  • [9] Effect of phosphorus on the hydrodesulfurization and hydrodenitrogenation performance of presulfided NiMo/Al2O3 catalyst
    Xiang C.-E.
    Chai Y.-M.
    Fan J.
    Liu C.-G.
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2011, 39 (05): : 355 - 360
  • [10] Investigation of the mechanism of the hydrodenitrogenation of n-hexylamines over sulfided NiMo/γ-Al2O3
    Zhao, YG
    Kukula, P
    Prins, R
    JOURNAL OF CATALYSIS, 2004, 221 (02) : 441 - 454
12345