THEORETICAL DIPOLE-MOMENT FOR THE X(2)PI STATE OF NO

被引:52
|
作者
LANGHOFF, SR
BAUSCHLICHER, CW
PARTRIDGE, H
机构
[1] NASA Ames Research Center, Moffett Field
关键词
D O I
10.1016/0009-2614(94)00501-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dipole moment function for the X 2PI state of NO is studied as a function of the completeness in both the one- and n-particle spaces. Einstein coefficients are presented that are significantly more accurate than previous tabulations for the higher vibrational levels. The theoretical values give considerable insight into the limitations of recently published ratios of Einstein coefficients measured by spectrally resolved infrared chemiluminescence.
引用
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页码:416 / 422
页数:7
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