SOLID-PHASE THERMAL-REACTIONS OF NICKEL(II) COMPLEXES CONTAINING DL-4-METHYL-1,2-PENTANEDIAMINE

被引：3

作者：

IHARA, Y

FUKUI, T

机构：

[1] Laboratory of Chemistry, Faculty of Education, Kanazawa University, Kanazawa

来源：

THERMOCHIMICA ACTA | 1994年 / 236卷

关键词：

D O I：

10.1016/0040-6031(94)80268-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal reactions of bis(dl-4-methyl-1,2-pentanediamine)nickel(II) complexes have been studied in the solid phase. A new example of square-planar (low spin) to octahedral (high spin) isomeric transformation was discovered in the chloride. The transformation proceeded endothermically (DELTAH = 3.50 kJ mol-1) and was accompanied by a reversible thermochromism from yellow to violet-blue on heating.

引用

页码：199 / 203

页数：5

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