SYNTHESIS AND CHARACTERIZATION OF A DIMOLYBDENUM (V)COMPLEX

被引：0
|
作者：
QIU, W
LIU, JZ
ZHENG, XF
FAN, YG
SUN, CT
HUANG, QJ
ZHANG, JW
机构：
[1] JILIN UNIV,DEPT CHEM,JILIN 130023,PEOPLES R CHINA
[2] JILIN UNIV,KEY LAB MOLEC SPECTRUM & MOLEC STRUCT,CHANGCHUN 130023,PEOPLES R CHINA
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1993年 / 30卷 / 11期
关键词：
D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new dimolybdenum (V) complex containing a trityl cation[(C6H4Cl)2C(Ph)]2[Mo2(mu-Cl)3Cl4O2][Mo2(mu-Cl)2Cl4O2 (mu-OCOPh)] has been obtained in the reaction of PhCl with benzoyl peroxide (PhCO2)2 and MoCl5. Its crystal structure has been determined by X-ray diffraction methods. Spectroscopic characterization of the compound and ASED-MO calculation of the trityl cation are reported.
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页码：1039 / 1048
页数：10
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