SYNTHESIS OF THE NEW TRIPODAL LIGAND TRIS-[3-(2'-PYRIDYL)PYRAZOL-1-YL]HYDROBORATE, AND THE CRYSTAL-STRUCTURE OF ITS EUROPIUM(III) COMPLEX

被引：129
|
作者：
AMOROSO, AJ [1 ]
THOMPSON, AMC [1 ]
JEFFERY, JC [1 ]
JONES, PL [1 ]
MCCLEVERTY, JA [1 ]
WARD, MD [1 ]
机构：
[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 24期
关键词：
D O I：
10.1039/c39940002751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The new tripodal ligand tris-[3-(2'-pyridyl)pyrazol-1-yl]hydroborate (L(-)), comprising three N,N-bidentate chelating arms linked by the epical boron atom, has been synthesized; the crystal structure of [EuL(MeOH)(2)F][PF6] reveals the nine-coordinate metal lying within the hexadentate ligand cavity.
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收藏
页码：2751 / 2752
页数：2
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