SYNTHESIS AND ABSOLUTE-CONFIGURATION OF (+)-GONYAULINE - A MODULATING SUBSTANCE OF BIOLUMINESCENT CIRCADIAN-RHYTHM IN THE UNICELLULAR ALGA GONYAULAX-POLYEDRA

被引：11
|
作者：
NAKAMURA, H
OHTOSHI, M
SAMPEI, O
AKASHI, Y
MURAI, A
机构：
[1] Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 20期
关键词：
GONYAULINE; PERIOD-SHORTENING SUBSTANCE; BIOLUMINESCENT CIRCADIAN RHYTHM; GONYAULAX-POLYEDRA; DINOFLAGELLATE;
D O I：
10.1016/S0040-4039(00)78868-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboxylic acid (3a) and the absolute configuration was established as 1R, 2R.
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页码：2821 / 2822
页数：2
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