CONTROLLED SYNTHESIS OF (1,3-TERT-BU2-C5H3)2TICL2 AND (1,3-TERT-BU2-C5H3)TICL3 - CRYSTAL-STRUCTURE AND REACTIONS OF (1,3-TERT-BU2-C5H3)TICL3

被引：16

作者：

JIBRIL, I ^{[1
]}

ABUORABI, S ^{[1
]}

KLAIB, SA ^{[1
]}

IMHOF, W ^{[1
]}

HUTTNER, G ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 433卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80151-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds (1,3-tBu2C5H3)2TiCl2, (I) and (1,3-tBu2C5H3)TiCl3 (II) were prepared in good yields from TiCl4 and (1,3-tBu2-C5H3)Li. Reactions of II with methanol, ethane-1,2-diol, sodium oxalate, and 2-pyrazine carboxylic acid afforded various organotitanium complexes. The crystal structure of II was determined.

引用

页码：253 / 259

页数：7

共 50 条

[1] Polymerization of isoprene with η5-C5H4(tert-Bu)TiCl3/MAO catalyst
Miyazawa, A
Kase, T
Shibuya, T
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (08) : 1841 - 1844
[2] INNER-SHELL SPECTROSCOPY OF (ETA-5-C5H5)2TICL2, (ETA-5-C5H5)TICL3, AND TICL4
WEN, AT
HITCHCOCK, AP
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1993, 71 (10): : 1632 - 1644
[3] SULFURIZATION REACTIONS OF P5C5-TERT-BU5 AND P5C5-TERT-BU5H2 - CRYSTAL AND MOLECULAR-STRUCTURE OF THE ETHANOL ADDUCT OF P5C5-TERT-BU5H2S3
BARTSCH, R
HITCHCOCK, PB
NIXON, JF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 433 (03) : C11 - C13
[4] Crystal structures of (η5-C5Me5)TiCl3 and (η5-C5Me4H)TiCl3
Pevec, A
[J]. ACTA CHIMICA SLOVENICA, 2003, 50 (02) : 199 - +
[5] Di-tert-butylcyclopentadienyl complexes of europium and ytterbium:: synthesis and crystal structures of (1,3-Bu(t)2C5H3)2Eu•THF, (1,3-Bu(t)2C5H3)(C5Me5)Yb•THF, and (1,3-Bu(t)2C5H3)2Yb(μ2-Cl)2Li(THF)2
Khvostov, AV
Bulychev, BM
Belsky, VK
Sizov, AI
[J]. RUSSIAN CHEMICAL BULLETIN, 1999, 48 (11) : 2162 - 2166
[6] ADDUCTS OF PHOSPHINES WITH INORGANIC AND ORGANOMETALLIC DERIVATIVES OF TITANIUM-IV .1. H-1 NMR INVESTIGATIONS ON LEWIS COMPLEXES OF (CH3)2(C6H5)P WITH TICL4 TICL3(OC2H5), (PI-C5H5) TICL3, (CH3)TICL3 AND (CH3)TI(OIC3H7)3
PELLEGATTA, JL
BASSOBERT, M
GERVAIS, D
[J]. JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1977, 74 (03) : 311 - 316
[7] MONO-TERT-BUTYLCYCLOPENTADIENYL AND DI-TERT-BUTYLCYCLOPENTADIENYL CARBONYL-COMPLEXES OF IRON AND MOLYBDENUM - CRYSTAL-STRUCTURE OF [CP''MO(CO)2]2 (CP'' = ETA-5-C5H3-TERT-BU2-1,3)
SCHEER, M
SCHUSTER, K
SCHENZEL, K
HERRMANN, E
JONES, PG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 600 (09): : 109 - 119
[8] Further study of the agostic molecule, TiCl3 (dmpe) C2H5
Cotton, FA
Petrukhina, MA
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (06) : 195 - 196
[9] Effect of ligand in ethylene/styrene copolymerization by [Me2Si(C5Me4)(NR)]TiCl2 (R = tert-Bu, cyclohexyl) and (1,3-Me2C5H3)TiCl2(O-2,6-iPr2C6H3)-MAO catalyst system
Nomura, K
Okumura, H
Komatsu, T
Naga, N
Imanishi, Y
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 190 (1-2) : 225 - 234
[10] MONO-TERT-BUTYLCYCLOPENTADIENYLCARBONYL AND DI-TERT-BUTYLCYCLOPENTADIENYLCARBONYL COMPLEXES OF MANGANESE, IRON, COBALT AND RHODIUM - CRYSTAL-STRUCTURE OF [CPXFE(CO)2]2 (CPX = ETA5-C5H3((T)BU)R-1,3 (R = H, (T)BU)
SCHEER, M
SCHUSTER, K
BECKER, U
KRUG, A
HARTUNG, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 460 (01) : 105 - 110

← 1 2 3 4 5 →