KINETICS OF EPOXIDATION OF 2-METHYL-2-PENTENE

被引：5
|
作者：
KURTEV, K
KECHAIOVA, D
机构：
[1] Department of Organic Synthesis, Higher Institute of Chemical Technology, Burgas
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 49卷 / 02期
关键词：
D O I：
10.1007/BF02067705
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of epoxidation of 2-methyl-2-pentene with cumene hydroperoxide catalyzed by MoO2(acac)2 has been studied in the temperature range of 35-65-degrees-C. The observed kinetic behavior is consistent with the formation of a hydroperoxide-catalyst complex and a simple competitive inhibition step, involving the formation of an inactive epoxide-catalyst complex. The reaction parameters have been calculated.
引用
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页码：369 / 376
页数：8
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