USING DEUTERIUM NMR LINE-SHAPES TO ANALYZE LYOTROPIC LIQUID-CRYSTALLINE PHASE-TRANSITIONS

Deuterium quadrupole NMR line shapes were simulated to match experimental spectra of liquid crystalline phases observed in the cesium and sodium n-tetradecanoate-D2O Systems. The line shapes of single-phase samples with both uniaxial and biaxial symmetry were accurately simulated. Line shape simulations were matched to experimental spectra by minimizing the sum of squared residuals on the basis of local intensity maxima and minima. The line shape parameters optimized were the quadrupole splitting DELTA-nu-Q, the spin-spin relaxation time T2, and, in the case of biaxial spectra, the aggregate asymmetry parameter-eta-D. The line shapes of multiple-phase samples were also accurately simulated by optimizing the relative amounts of each phase. The method can be used to accurately determine tie-line and tie-triangle end points in multiple-phase liquid crystal samples. Among the illustrative liquid crystalline transitions provided are hexagonal to ribbon phase, ribbon to lamellar phase, and ribbon to viscous isotropic phase.