THEORETICAL ESTIMATIONS OF 3RD-ORDER OPTICAL NONLINEARITIES FOR ONE-DIMENSIONAL METAL CHAINS

被引：0
|
作者：
FUKAYA, T
KAMATA, T
MIZUNO, M
机构：
[1] National Institute of Materials and Chemical Research, Tsukuba, Ibaraki, 305
来源：
SYNTHETIC METALS | 1995年 / 71卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)03007-S
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Third order optical nonlinearities of linear metal chains, which are formed in crystals and vacuum evaporated thin films of metal-dioxime complexes, are analyzed by using CNDO/SD-CI calculations. Intermolecular exicitonic states are revealed to act very important rolls to the excellent nonlinearities of the linear metal chains. The molecular hyperpolarizabilities gamma increase with seventh power of the metal chain length.
引用
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页码：1693 / 1694
页数：2
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