STRUCTURE AND REACTIVITY OF COPPER(II) CARBOXYLATES .1. COPPER(II) DIPICOLINATES

被引：13
|
作者：
SILEO, EE
QUINTEROSRIVERO, MF
RIVERO, BE
RIGOTTI, G
BLESA, MA
机构：
[1] UNLP,FAC CIENCIAS EXACTAS,DEPT FIS,CRISTALOG LAB,RA-1900 LA PLATA,ARGENTINA
[2] COMIS NACL ENERGIA ATOM,DEPT QUIM REACTORES,RA-1429 BUENOS AIRES,ARGENTINA
来源：
SOLID STATE IONICS | 1994年 / 73卷 / 1-2期
关键词：
COPPER CARBOXYLATES; DEHYDRATION; DIPICOLINATE; STRUCTURE; THERMAL DECOMPOSITION;
D O I：
10.1016/0167-2738(94)90275-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The crystal and molecular structures of a series of salts formed by copper(II) with dipicolinic acid were used to interpret the dehydration behavior. The morphology of single crystals dehydration of Cu (dipic) . 2H2O (monoclinic and triclinic symmetry), Cu(dipic) . 3H2O and Cu(dipic) (H-2dipic).xH2O was shown to be governed by the arrangement of water molecules along specific orientations.
引用
收藏
页码：153 / 159
页数：7
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