SURFACE-TENSION MEASUREMENTS OF LIQUID-IRON NICKEL SULFUR TERNARY-SYSTEM USING THE ELECTROMAGNETIC OSCILLATING DROPLET TECHNIQUE

被引:8
|
作者
LEE, HK
FROHBERG, MG
HAJRA, JP
机构
[1] Institute of General Metallurgy, Technical University Berlin, D-1000 Berlin
[2] Technical University Berlin, Now at Indian Institute of Science, Bangalore
关键词
ELECTROMAGNETIC OSCILLATING DROPLET TECHNIQUE; SURFACE TENSION OF IRON SULFUR ALLOYS; SURFACE TENSION OF IRON NICKEL SULFUR ALLOYS; SURFACE ACTIVE ELEMENT; POSITIVE TEMPERATURE COEFFICIENT OF SURFACE TENSION; ISO-SURFACE TENSION DIAGRAM;
D O I
10.2355/isijinternational.33.833
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Surface tensions of liquid iron-nickel-sulphur ternary alloys as a function of the composition and the temperature have been determined by the oscillating droplet method combined with electromagnetic levitation technique. The natural frequency of the oscillating droplet was evaluated using a Fourier analyzer, and the influence of magnetic field strength on the surface tension was also considered. The temperature dependence of surface tension for the liquid iron and iron-nickel melts containing the surface active element sulphur were found to be positive. This effect may be due to the change of the sign in the entropy terms for the bulk and surface phase caused by the reduced mobility of the surface atoms. Furthermore, iso-surface tension diagram for the iron-nickel-sulphur ternary system at 1 873 K is given and discussed.
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页码:833 / 838
页数:6
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