[MOH4(DPPE)(2)].THF (DPPE=PH(2)PCH(2)CH(2)PPH(2), THF=TETRAHYDROFURAN)

被引：8
|
作者：
POMBEIRO, AJL [1 ]
HILLS, A [1 ]
HUGHES, DL [1 ]
RICHARDS, RL [1 ]
机构：
[1] UNIV SUSSEX,AFRC,INST PLANT SCI RES,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S0108270194007559
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of tetrahydridobis[1,2-bis(diphenyl-phosphino)ethane-P,P']molybdenum(IV), [MoH4-(dppe)(2)] (dppe = Ph(2)PCH(2)CH(2)PPh(2)), is reported as the tetrahydrofuran solvate. The molecule has dodecahedral geometry with the four P atoms in the B sites and the hydrides in the A sites. Mean Mo-P and Mo-H distances are 2.420(3) and 1.67(2) Angstrom, respectively.
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页码：23 / 26
页数：4
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