MICROBIAL HYDROXYLATION OF PRECURSORS OF SINENSAL

被引：0
|
作者：
ABRAHAM, WR [1 ]
ARFMANN, HA [1 ]
GIERSCH, W [1 ]
机构：
[1] FIRMENICH CO,GENEVA,SWITZERLAND
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES | 1992年 / 47卷 / 11-12期
关键词：
MICROBIAL HYDROXYLATION; SESQUITERPENOIDS; SINENSAL; FARNESENE SULFONE; MONOCYCLOFARNESANES;
D O I：
暂无
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In order to produce the important flavour compound sinensal microbial omega-hydroxylation of farnesene and its sulfone derivative were investigated. While farnesene proved to be a poor substrate, its sulfone could be hydroxylated to the omega-hydroxyfarnesene sulfones in up to 27% yield. Some strains could discriminate between the E- and Z-configurated substrate. In low yields products hycroxylated at different positions and two monocyclofarnesane derivatives could also be isolated.
引用
收藏
页码：851 / 858
页数：8
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