HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF [HN(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)]

被引：91
|
作者：
BONAVIA, G
DEBORD, J
HAUSHALTER, RC
ROSE, D
ZUBIETA, J
机构：
[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244
[2] NEC RES INST,PRINCETON,NJ 08540
来源：
CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 11期
关键词：
D O I：
10.1021/cm00059a002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrothermal reactions of VCl4 with phosphorous acid H3PO3, in the presence of the appropriate organoamine, yield new examples of the oxovanadium(IV)-phosphite class of materials, [HN(Me)(CH2CH2)(2)N(Me)H] [(VO)(4)(OH)(2)(HPO3)(4)] (1), [H2N(CH2CH2)(2)NH2] [(VO)(3)(HPO3)(4)(H2O)(2)] (2), and [VO(HPO3)(H2O)] (3). The 3-D framework structure adopted by 3 is illustrated.
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页码：1995 / &
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