EFFECTIVE RING FORMATIONS AND NATURAL PRODUCT SYNTHESES

被引：13
|
作者：
FUKUMOTO, K
机构：
[1] Faculty of Pharmaceutical Sciences, Tohoku University
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1994年 / 52卷 / 01期
关键词：
INTRAMOLECULAR DIELS-ALDER REACTION; INTRAMOLECULAR DOUBLE MICHAEL REACTION; TANDEM MICHAEL-ALDOL REACTION; TANDEM MICHAEL-CLAISEN REACTION; DOUBLE MICHAEL-ALDOL REACTION; TOTAL SYNTHESIS OF TERPENES; TOTAL SYNTHESIS OF STEROIDS; TOTAL SYNTHESIS OF ALKALOIDS;
D O I：
10.5059/yukigoseikyokaishi.52.2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Simple and effective synthetic methods of polycylic ring systems in intramolecular reactions are presented. The first example is Diels-Alder reaction, which has been applied to total synthesis of steroids and terpenes. The intramolecular double Michael reaction is the second case, whose mechanism and application to natural product synthesis are also discussed. In addition, some related reactions of the latter are described.
引用
收藏
页码：2 / 18
页数：17
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