Aerobic oxidations on metal macrocycles encapsulated in zeolites

被引：0
|
作者：
Zsigmond, A
Notheisz, F
Szegletes, Z
Backvall, JE
机构：
[1] INST BIOPHYS,BIOL RES CTR,H-6701 SZEGED,HUNGARY
[2] UPPSALA UNIV,DEPT ORGAN CHEM,S-75121 UPPSALA,SWEDEN
来源：
CATALYSIS BY MICROPOROUS MATERIALS | 1995年 / 94卷
关键词：
D O I：
暂无
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Zeolite-encapsulated Fe-phthalocyanine and Co-salophen catalysts were used in the palladium-catalyzed aerobic oxidation of hydroquinone to benzoquinone, in the oxidation of 1-octene to 2-octanone and in the allylic oxidation of cyclohexene to 3-acetoxycyclohexene. These catalysts proved to be active in the above reactions and they were stable towards self-oxidation and it was possible to reuse them in subsequent runs. The specific activity of the encapsulated Fe-phthalocyanine catalyst was about four times higher than those of the free complex.
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页码：728 / 735
页数：8
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