Synthesis and characterization of Cu(II), Co(II), Ni(II) complexes with Schiff bases derived from 3-(4-chlorophenoxymethyl)-4-amino-5-mercapto-1,2,4-triazole

被引：0

作者：

Reddy, Vidyavati ^{[1
]}

Patil, Nirdosh ^{[2
]}

Reddy, Tukaram ^{[1
]}

Angadi, S. D. ^{[1
]}

机构：

[1] Gulbarga Univ, Dept Studies & Res Chem, Gulbarga 585106, India

[2] Gulbarga Univ, Appa Inst Engn & Technol, Gulbarga 585106, India

来源：

ORIENTAL JOURNAL OF CHEMISTRY | 2008年 / 24卷 / 01期

关键词：

Triazoles; metal complexes; spectral and magnetic susceptibility;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new bidentate Schiff base ligands derived from 3-(4-chlorophenoxymethyl)-4-amino-5mercapto-1,2,4-triazole with substituted salicylaldehyde and its Cu(II), Co(II) and Ni(II) complexes have been synthesized and characterized by elemental analysis, IR, electronic, (HNMR)-H-1 and ESR spectra. The analytical data and spectral data reveals that the composition of the complexes to be ML2 (H2O)(2) where M = Cu(II), Co(II), Ni(II) and are non-electrolytic in nature. It is found that these complexes exhibit octahedral geometry. The various spectral data shows the monobasic bidentate character of the ligand coordinating through 'N' of azomethine and 'O' of phenyl group.

引用

页码：201 / 206

页数：6

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