1ST GAS-PHASE SPECTRUM OF THE ALUMINUM CARBIDE MOLECULE - THE B4-SIGMA--X4-SIGMA-SYSTEM

被引:51
|
作者
BRAZIER, CR
机构
[1] Phillips Laboratory/RKFE, Edwards Air Force Base
来源
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 04期
关键词
D O I
10.1063/1.464160
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The aluminum carbide radical has been seen in the gas phase for the first time. The B 4SIGMA-X 4SIGMA- system near 22 000 cm-1 was observed in emission from a hollow cathode source. Three vibrational sequences were detected: DULTAv = 0, -1, and -2, and a full rotational analysis was performed on the five strongest bands, 0-0, 1-1, 0-1, 1-2, and 2-3.
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页码:2790 / 2797
页数:8
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