ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .8. SYNTHESIS AND CHARACTERIZATION OF (METH)ACRYLIC END-FUNCTIONALIZED POLYMERS - MACROMONOMERS AND TELECHELICS

被引：30

作者：

VARSHNEY, SK ^{[1
]}

BAYARD, P ^{[1
]}

JACOBS, C ^{[1
]}

JEROME, R ^{[1
]}

FAYT, R ^{[1
]}

TEYSSIE, P ^{[1
]}

机构：

[1] UNIV LIEGE,CTR EDUC & RES MACROMOLEC,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,SART B6,B-4000 LIEGE,BELGIUM

来源：

MACROMOLECULES | 1992年 / 25卷 / 21期

关键词：

D O I：

10.1021/ma00047a003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Tailor-made poly(tert-butyl acrylate) macromonomers, which are useful building blocks for the synthesis of comb or multiblock copolymers, have been successfully synthesized by deactivation of living PtBA macroanions with suitable electrophiles bearing either styrene or methacrylic unsaturation. Mono- or bifunctional initiators such as sec-butyllithium or naphthalenyllithium can be used. When these initiators were modified by LiCl as a mu-type ligand, the macroanions which are known to be living were functionalized with high efficiency. Characterization of the various macromonomers was performed using H-1 NMR spectroscopy and SEC.

引用

页码：5578 / 5584

页数：7

共 36 条

[1] KINETICS AND MECHANISMS IN THE ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS
MULLER, AHE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 72 - POLY
[2] A COMPARISON OF GROUP TRANSFER AND ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS
WEBSTER, OW
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 60 : 287 - 296
[3] STUDY OF THE PROPAGATION CENTER IN THE ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .1. SPECTROSCOPIC STUDY OF METHYL 2-LITHIOISOBUTYRATE, AN INITIATOR FOR THE ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS
KRIZ, J
DYBAL, J
VLCEK, P
JANATA, M
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1994, 195 (09) : 3039 - 3056
[4] ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .21. ANIONIC SEQUENTIAL POLYMERIZATION OF 2-ETHYLHEXYL ACRYLATE AND METHYL-METHACRYLATE
WANG, JS
JEROME, R
BAYARD, P
TEYSSIE, P
MACROMOLECULES, 1994, 27 (18) : 4908 - 4913
[5] Synthesis of end-functionalized polymers by means of living anionic polymerization .8. Reactions of living anionic polymers with alpha,omega-dihaloalkanes
Hirao, A
Tohoyama, M
Nakahama, S
MACROMOLECULES, 1997, 30 (12) : 3484 - 3489
[6] ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .5. SYNTHESIS, CHARACTERIZATION, AND MODIFICATION OF POLYSTYRENE POLY(TERT-BUTYL ACRYLATE) DIBLOCK AND TRIBLOCK COPOLYMERS
HAUTEKEER, JP
VARSHNEY, SK
FAYT, R
JACOBS, C
JEROME, R
TEYSSIE, P
MACROMOLECULES, 1990, 23 (17) : 3893 - 3898
[7] ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .17. LIGATED ANIONIC LIVING POLYMERIZATION OF 2-ETHYLHEXYL ACRYLATE AS PROMOTED BY POLYDENTATE LITHIUM ALKOXIDES
WANG, JS
BAYARD, P
JEROME, R
VARSHNEY, SK
TEYSSIE, P
MACROMOLECULES, 1994, 27 (18) : 4890 - 4895
[8] ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .19. EFFECT OF VARIOUS TYPES OF LIGANDS OTHER THAN LITHIUM-CHLORIDE ON THE STEREOCHEMISTRY OF ANIONIC-POLYMERIZATION OF METHYL-METHACRYLATE
WANG, JS
JEROME, R
TEYSSIE, P
MACROMOLECULES, 1994, 27 (18) : 4902 - 4907
[9] ANIONIC-POLYMERIZATION OF ACRYLIC-MONOMERS .6. SYNTHESIS, CHARACTERIZATION, AND MODIFICATION OF POLY(METHYL METHACRYLATE) POLY(TERT-BUTYL ACRYLATE) DIBLOCK AND TRIBLOCK COPOLYMERS
VARSHNEY, SK
JACOBS, C
HAUTEKEER, JP
BAYARD, P
JEROME, R
FAYT, R
TEYSSIE, P
MACROMOLECULES, 1991, 24 (18) : 4997 - 5000
[10] ANIONIC-POLYMERIZATION OF (METH)ACRYLIC MONOMERS .22. ANIONIC-POLYMERIZATION OF TERT-BUTYL METHACRYLATE IN TOLUENE/THF MIXTURES - A PRELIMINARY APPROACH TO THE ROLE OF SOLVATION LIGATION EQUILIBRIA
WANG, JS
ZHANG, H
JEROME, R
TEYSSIE, P
MACROMOLECULES, 1995, 28 (06) : 1758 - 1764

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