ON THE REACTIVITY OF SILAETHENE ME2SI=C(SIME3)2 - STEREOSPECIFICITY OF DIELS-ALDER REACTIONS WITH HEXADIENES

被引：11
|
作者：
WIBERG, N
FISCHER, G
WAGNER, S
机构：
[1] Institut Für Anorganische Chemie, Universität München, München, D-8000
来源：
CHEMISCHE BERICHTE | 1991年 / 124卷 / 04期
关键词：
SILAETHENE; DIELS-ALDER REACTION;
D O I：
10.1002/cber.19911240416
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[4 + 2] Cycloaddition of trans,trans- and cis,trans-2,4-hexadiene to silaethene Me2Si = C(SiMe3)2 (1) takes place stereo-specifically in one step with formation of 3 and 4, respectively. In addition, both reactions lead to ene products 5, 6.
引用
收藏
页码：769 / 771
页数：3
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