SYNTHESIS AND CHARACTERIZATION OF NOVEL HOMOLEPTIC AND HETEROLEPTIC NONAISOPROPOXODIZIRCONATOSAMARIUM(III) COMPLEXES

被引：10

作者：

GARG, G ^{[1
]}

SINGH, A ^{[1
]}

MEHROTRA, RC ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

POLYHEDRON | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)84332-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heterobimetallic isopropoxide derivatives of samarium(III) of the types [Cl3-nSm{Zr2(OPri)9}n] (n = 1, 2 or 3) have been prepared by the interaction Of SMCl3. 3PriOH with K(Zr2(OPri)9} in the desired molar (I : 1, 1: 2 or 1: 3) ratios in benzene. Chloride-isopropoxo (or tetraisopropoxoaluminato) exchange reactions have led to the formation of interesting hetero-(bi- or tri-) metal isopropoxides of samarium(III), L3-.SM{Zr2(OPri)9}n [L = OPri, n = 1 or 2; L = Al(OPri)4, n = 1]. All these products have been characterized by elemental analyses and spectroscopic (IR, NMR) studies.

引用

下载

页码：1399 / 1402

页数：4

共 50 条

[1] Synthesis and characterization of homoleptic and heteroleptic ruthenium polypyridine complexes
Bhuiyan, Anwar A.
Kudo, Shotaro
Wade, Christina
Davis, Robby F.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[2] Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh, Anuradha
Teegardin, Kip
Kelly, Megan
Prasad, Kariate S.
Krishnan, Sadagopan
Weaver, Jimmie D.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 776 : 51 - 59
[3] SYNTHESIS AND CHARACTERIZATION OF NOVEL HOMOLEPTIC AND HETEROLEPTIC ALKOXOMETALLATES OF MANGANESE(II)
DUBEY, RK
SINGH, A
MEHROTRA, RC
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1992, 31 (03): : 156 - 159
[4] Synthesis and Characterization of Homoleptic and Heteroleptic Complexes Involving Dithiocarbamates, Triphenylphosphine, and Nickel(II)
Rani, Palanisamy Jamuna
Thirumaran, Subbiah
Ciattini, Samuele
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2013, 188 (06) : 778 - 789
[5] Synthesis and structure of heteroleptic and homoleptic thiomethyl nickel complexes
Becke, F
Ruffer, T
Boese, R
Blaser, D
Steinborn, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 545 : 169 - 178
[6] Syntheses and Molecular Structures of Heteroleptic and Homoleptic Antimony(iii) Tetrafluorophenylethylenediamidate Complexes
Aldabbagh, Areej K.
Junk, Peter C.
Wang, Jun
AUSTRALIAN JOURNAL OF CHEMISTRY, 2020, 73 (5-6) : 504 - 510
[7] Heteroleptic and Homoleptic Iron(III) Complexes with a Tris(N-Heterocyclic Carbene) Borate Ligand: Synthesis, Characterization, and Catalytic Application
Sato, Yuna
Okamura, Masaya
Hikichi, Shiro
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (14)
[8] Synthesis and characterization of tris(heteroleptic) diimine complexes of chromium(III)
Donnay, Edward G.
Schaeper, James P.
Brooksbank, Richard D.
Fox, Jennifer L.
Potts, Rebekah G.
Davidson, Rush M.
Wheeler, John F.
Kane-Maguire, Noel A. P.
INORGANICA CHIMICA ACTA, 2007, 360 (10) : 3272 - 3280
[9] SYNTHESIS, REACTIONS AND CHARACTERIZATION OF NOVEL HOMOLEPTIC ISOPROPOXOMETALLATES OF SAMARIUM(III)
GARG, G
SINGH, A
MEHROTRA, RC
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1995, 34 (06): : 484 - 486
[10] Novel Homoleptic and Heteroleptic Pt(II) β-oxodithiocinnamic ester Complexes: Synthesis, Characterization, Interactions with 9-methylguanine and Antiproliferative Activity
Farh, Micheal K. K.
Haefner, Norman
Goerls, Helmar
Runnebaum, Ingo B. B.
Weigand, Wolfgang
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2023, 649 (6-7):

← 1 2 3 4 5 →