VOLTAMMETRIC AND NMR-STUDIES OF A BIS(FERROCENECARBOXAMIDE)-SUBSTITUTED DIAZA 18-CROWN-6 RECEPTOR THAT SIMULTANEOUSLY COMPLEXES AND ELECTROCHEMICALLY RECOGNIZES BOTH CATIONS AND ANIONS

被引：41

作者：

BEER, PD

CHEN, Z

OGDEN, MI

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 02期

关键词：

D O I：

10.1039/ft9959100295

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Voltammetric and NMR investigations of a bis(ferrocenecarboxamide)-substituted diaza 18-crown-6 receptor in an aprotic environment have been carried out. This receptor molecule can complex metal cations or anions individually and can accommodate both a cation and anion. The binding of anions is significantly enhanced by the presence of a bound metal cation, with selectivity for HSO4- over Cl-. The receptor is capable of electrochemically recognising the complexed anions, cations and anion/cation pairs.

引用

页码：295 / 302

页数：8