NON-TYPICAL WULFF SHAPES IN A CORNER - A MICROSCOPIC DERIVATION

被引:6
|
作者
DECONINCK, J
FRUTTERO, J
ZIERMANN, A
机构
[1] Université de Mons-Hainaut, 7000 Mons, 20, Place du Parc
来源
PHYSICA A | 1993年 / 196卷 / 03期
关键词
D O I
10.1016/0378-4371(93)90198-D
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A complete microscopic analysis of the equilibrium shape of a droplet in a corner between two walls is given within a Gaussian SOS model. We derive a statistical mechanical proof of the Winterbottom and the Summertop constructions for the equilibrium shapes, including a proof of generalized Young relations for inclined walls. We discuss a phase diagram with convexity-concavity transitions and wetting transitions induced by changing the inclination of the walls. A possible degeneracy of the solutions of the thermodynamic variational problem at the convexity-concavity transition point is discussed in the Gaussian model from a statistical mechanical point of view.
引用
收藏
页码:320 / 334
页数:15
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