TRANSITION-METAL-CATALYZED METATHESIS OF PHOSPHORUS-PHOSPHORUS DOUBLE-BONDS

被引：32
|
作者：
DILLON, KB [1 ]
GIBSON, VC [1 ]
SEQUEIRA, LJ [1 ]
机构：
[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 23期
关键词：
D O I：
10.1039/C39950002429
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
W(PMe(3))(6) is an efficient chloride ion abstracting reagent for the synthesis of RP=PR species from RPCl(2) precursors; moreover, the W(PMe(3))(6)-RPCl(2) solutions catalyse the exchange of the diphosphene PR end-groups via a mechanism closely related to the olefin metathesis process.
引用
收藏
页码：2429 / 2430
页数：2
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