A NICKEL(II) AZIDE CUBANE - CHARACTERIZATION OF THE MAGNETIC EXCHANGE INTERACTIONS MEDIATED BY A TRIPLY BRIDGING AZIDE GROUP BOUND END-ON

被引：97

作者：

HALCROW, MA

HUFFMAN, JC

CHRISTOU, G

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[2] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期

关键词：

COMPLEXES WITH NITROGEN LIGANDS; COMPLEXES WITH OXYGEN LIGANDS; CUBANES; MAGNETIC PROPERTIES; NICKEL COMPOUNDS;

D O I：

10.1002/anie.199508891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ferromagnetic exchange interaction that is not influenced by the distortion of the cubane framework of 1 (see picture; only the O atoms of the EtOH and dbm− ligands are shown) and is mediated by the end‐on‐coordinated μ3‐azide bridges has been detected for the first time. Although the unusual [M4(η1‐μ3‐N3)4] core is also displayed by a Pt complex, 1 is the first parmagnetic example. (dbmH = dibenzoylmethane). (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：889 / 891

页数：3

共 35 条

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